全文获取类型
收费全文 | 11931篇 |
免费 | 1293篇 |
国内免费 | 1103篇 |
专业分类
化学 | 973篇 |
晶体学 | 5篇 |
力学 | 1051篇 |
综合类 | 286篇 |
数学 | 10227篇 |
物理学 | 1785篇 |
出版年
2024年 | 11篇 |
2023年 | 120篇 |
2022年 | 149篇 |
2021年 | 197篇 |
2020年 | 287篇 |
2019年 | 284篇 |
2018年 | 336篇 |
2017年 | 369篇 |
2016年 | 386篇 |
2015年 | 270篇 |
2014年 | 470篇 |
2013年 | 998篇 |
2012年 | 524篇 |
2011年 | 673篇 |
2010年 | 609篇 |
2009年 | 748篇 |
2008年 | 809篇 |
2007年 | 767篇 |
2006年 | 762篇 |
2005年 | 656篇 |
2004年 | 581篇 |
2003年 | 551篇 |
2002年 | 524篇 |
2001年 | 413篇 |
2000年 | 398篇 |
1999年 | 348篇 |
1998年 | 321篇 |
1997年 | 306篇 |
1996年 | 211篇 |
1995年 | 202篇 |
1994年 | 149篇 |
1993年 | 135篇 |
1992年 | 117篇 |
1991年 | 78篇 |
1990年 | 77篇 |
1989年 | 49篇 |
1988年 | 41篇 |
1987年 | 36篇 |
1986年 | 37篇 |
1985年 | 48篇 |
1984年 | 46篇 |
1983年 | 24篇 |
1982年 | 42篇 |
1981年 | 26篇 |
1980年 | 31篇 |
1979年 | 23篇 |
1978年 | 23篇 |
1977年 | 18篇 |
1976年 | 12篇 |
1974年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 109 毫秒
61.
Spherical confinement of coulombic systems inside an impenetrable box: H atom and the Hulthén potential 下载免费PDF全文
Amlan K. Roy 《International journal of quantum chemistry》2015,115(15):937-947
The generalized pseudospectral method is used to study spherical confinement in two simple Coulombic systems: (i) well celebrated and heavily studied H atom (ii) relatively less explored Hulthén potential. In both instances, arbitrary cavity size as well as low and higher states are considered. Apart from bound state eigenvalues, eigenfunctions, expectation values, quite accurate estimates of the critical cage radius for H atom for all the 55 states corresponding to , are also examined. Some of the latter are better than previously reported values. Degeneracy and energy ordering under the isotropic confinement situation are discussed as well. The method produces consistently high‐quality results for both potentials for small as well as large cavity size. For the H atom, present results are comparable to best theoretical values, while for the latter, this work gives considerably better estimates than all existing work so far. © 2014 Wiley Periodicals, Inc. 相似文献
62.
Accuracy assessment of the linear Poisson–Boltzmann equation and reparametrization of the OBC generalized Born model for nucleic acids and nucleic acid–protein complexes 下载免费PDF全文
Federico Fogolari Alessandra Corazza Gennaro Esposito 《Journal of computational chemistry》2015,36(9):585-596
The generalized Born model in the Onufriev, Bashford, and Case (Onufriev et al., Proteins: Struct Funct Genet 2004, 55, 383) implementation has emerged as one of the best compromises between accuracy and speed of computation. For simulations of nucleic acids, however, a number of issues should be addressed: (1) the generalized Born model is based on a linear model and the linearization of the reference Poisson–Boltmann equation may be questioned for highly charged systems as nucleic acids; (2) although much attention has been given to potentials, solvation forces could be much less sensitive to linearization than the potentials; and (3) the accuracy of the Onufriev–Bashford–Case (OBC) model for nucleic acids depends on fine tuning of parameters. Here, we show that the linearization of the Poisson Boltzmann equation has mild effects on computed forces, and that with optimal choice of the OBC model parameters, solvation forces, essential for molecular dynamics simulations, agree well with those computed using the reference Poisson–Boltzmann model. © 2015 Wiley Periodicals, Inc. 相似文献
63.
The extrapolation scheme of correlation energy is revisited to evaluate the complete basis set limit from double‐zeta (DZ) and triple‐zeta levels of calculations. The DZ level results are adjusted to the standard asymptotic behavior with respect to the cardinal number, observed at the higher levels of basis sets. Two types of adjusting schemes with effective scaling factors, which recover errors in extrapolations with the DZ level basis set, are examined. The first scheme scales the cardinal number for the DZ level energy, while the second scheme scales the prefactor of the extrapolation function. Systematic assessments on the Gaussian‐3X and Gaussian‐2 test sets reveal that these calibration schemes successfully and drastically reduce errors without additional computational efforts. © 2015 Wiley Periodicals, Inc. 相似文献
64.
65.
Basis Sets Dependency in Constructing Spectroscopy-Accuracy Ab Initio Global Electric Dipole Moment Functions 下载免费PDF全文
Recently, more attention have been paid on the construction of dipole moment functions (DMF) using theoretical methods. However, the computational methods to construct DMFs are not validated as much as those for potential energy surfaces do. In this letter, using Ar...He as an example, we tested how spectroscopyaccuracy DMFs can be constructed using ab initio methods. We especially focused on the basis set dependency in this scenario, i.e., the convergence of DMF with the sizes of basis sets, basis set superposition error, and mid-bond functions. We also tested the explicitly correlated method, which converges with smaller basis sets than the conventional methods do. This work can serve as a pictorial sample of all these computational technologies behaving in the context of constructing DMFs. 相似文献
66.
本文主要概述了近年来核酸工具酶辅助的基于金属稳定同位素标记的电感耦合等离子体质谱(ICP-MS)检测方法在生物分析中的发展和应用,简要介绍了该方法在蛋白质、核酸及一些生物小分子检测中的应用。最后对核酸工具酶辅助的基于金属稳定同位素标记的电感耦合等离子体质谱(ICP-MS)检测方法的发展前景做了展望。 相似文献
67.
建立了气相色谱-质谱联用技术同时测定益智药材中16种多环芳烃(PAHs)的分析方法。最佳萃取条件为:取样品2.0 g,加入同位素内标后用无水乙醇、水混合溶解,以10 mL正己烷提取;提取液先过Florisil柱固相萃取,经氢氧化钾-乙醇溶液皂化,多环芳烃分子印迹柱固相萃取后,以5 mL二氯甲烷-正己烷(1∶1,体积比)进行洗脱;采用DB-EUPAH毛细管色谱柱进行分离,内标标准曲线法定量测定。在此条件下,16种多环芳烃的线性范围为1.0~200.0 μg/L(r2 ≥ 0.992 5);检出限(S/N=3)为0.3~1.0 μg/kg;在不同浓度(1、3、10 μg/kg)基质加标条件下,苯并[c]芴(BcFL)的加标回收率为65.4%~72.8%,日内相对标准偏差(RSD,n=6)为6.0%~7.4%,日间RSD(n=6)为8.5%;其他15种多环芳烃的加标回收率为89.3%~116%,日内RSD(n=6)为0.10%~6.1%,日间RSD(n=6)为1.2%~7.5%。该方法的前处理净化效果好、灵敏度高、准确度高,适用于益智药材中16种多环芳烃的定量检测。 相似文献
68.
Kengo Asai Prof. Dr. Aiko Fukazawa Prof. Dr. Shigehiro Yamaguchi 《Angewandte Chemie (International ed. in English)》2017,56(24):6848-6852
A near-infrared (NIR) polymethine dye ( 1 ), consisting of a cyclohepta[1,2-b;4,3-b′]dithiophene and two phenol moieties, was synthesized. This dye exhibited pH-responsive changes in its photophysical properties due to a two-step acid–base equilibrium that produced a protonated cation ( 1H+ ) and an anion ( 1− ). While 1H+ showed an intense fluorescence in the red region of the visible spectrum, 1− exhibited a strong absorption in the NIR region. The tropylium ion character in 1H+ induces high pKa1 and pKa2 values for 1 . Moreover, a stable radical ( 1. ) was prepared, which showed a NIR absorption band with a maximum at circa 1600 nm. The cyclic voltammogram of 1. revealed a two-step reversible redox process that produced 1− and the cation 1+ , which is different from 1H+ . These redox processes accompany drastic electrochromic changes in the vis–NIR region. Overall, 1 is susceptible to multiple interconversions between five forms, due to the multifaceted character of the cycloheptadithiophene skeleton. 相似文献
69.
考虑如下广义线性模型y_i=h(x~T_i,β)+e_i=1,2,…,n,其中e_i=G(…,ε_(i-1),ε_i),h是一个连续可导函数,ε_i是独立同分布的随机变量,并且它的期望为0,方差σ~2有限.本文给出了参数β的M估计,并且得到了该估计的Bahadur表示,该结论推广了线性模型的相关结论.应用M估计的Bahadur表示,得到了相依误差的线性回归模型,poisson模型,logistic模型和独立误差的广义线性模型等模型的渐近性质. 相似文献
70.
Modeling social‐ecological systems is difficult due to the complexity of ecosystems and of individual and collective human behavior. Key components of the social‐ecological system are often over‐simplified or omitted. Generalized modeling is a dynamical systems approach that can overcome some of these challenges. It can rigorously analyze qualitative system dynamics such as regime shifts despite incomplete knowledge of the model's constituent processes. Here, we review generalized modeling and use a recent study on the Baltic Sea cod fishery's boom and collapse to demonstrate its application to modeling the dynamics of empirical social‐ecological systems. These empirical applications demand new methods of analysis suited to larger, more complicated generalized models. Generalized modeling is a promising tool for rapidly developing mathematically rigorous, process‐based understanding of a social‐ecological system's dynamics despite limited knowledge of the system. 相似文献